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Azo dyes

Time:2020-09-18 16:12:28 CTR:

Introduction to testing


In the molecular structure of dyes, those containing azo groups (-N=N-) are collectively referred to as azo dyes. Often connected with one or more aromatic ring systems to form a conjugated system as the color body of the dye, distributed in almost all colors. Azo dyes are widely used in the dyeing and printing process of textiles, clothing, leather products, household fabrics, etc. .
When textiles, clothing and leather products are in direct contact with the human body, certain types of azo dyes mix with normal human metabolites (such as sweat) and undergo a reduction reaction to form carcinogenic The aromatic amine compound is then absorbed by the human body, which is extremely harmful to the human body. These azo dyes are carcinogenic azo dyes.

Test Ability


Serial number    

Substance name                      

CAS.NO.

1

O-toluidine

95-53-4

2

2,4-dimethylaniline

95-68-1

3

2,6-Dimethylaniline

87-62-7

4

anthranil

90-04-0

5

p-Chloroaniline

106-47-8

6

2,4,5-trimethylaniline

137-17-7

7

2-Methoxy-5-methylaniline

120-71-8

8

4-Chloro-o-toluidine

95-69-2

9

2,4-Diaminotoluene

95-80-7

10

2,4-Diaminoanisole

615-05-4

11

2-Naphthylamine

91-59-8

12

4-Aminobiphenyl

92-67-1

13

4,4-Diaminodiphenyl ether

101-80-4

14

Benzidine

92-87-5

15

4,4-Diaminodiphenylmethane

101-77-9

16

3,3-Dimethyl-4,4-diaminodiphenylmethane

838-88-0

17

3,3-Dimethylbenzidine

119-93-7

18

4,4-Diaminodiphenyl sulfide

139-65-1

19

3,3-Dichlorobenzidine

91-94-1

20

3,3-Dimethoxybenzidine

119-90-4

21

4,4-methylene-bis-(2-chloroaniline)

101-14-4

22

O-aminoazotoluene

97-56-3

23

5-Nitro-o-toluidine

99-55-8

24

4-Aminoazobenzene

60-09-3

 

Applicable standards


EN 14362-1:2012

Tests for banned azo dyes in textiles

EN 14362-3:2012

Textile 4-aminoazobenzene test

LFGB §64 BVL B 82.02-4:2013

Detection method for banned azo dyes in polyester for daily necessities

LFGB §64 BVL B 82.02-2:2013

The detection method of azo dyes forbidden in textiles for daily necessities testing

LFGB §64 BVL B 82.02-9:2008

Commodity testing banned azo dye-tetraaminoazobenzene testing method

GB/T 17592-2011

Test of banned azo dyes in textiles

GB/T 23344-2009

Textile 4-aminoazobenzene test

ISO 17234-1:2010

Leather banned azo dye test

ISO 17234-2:2011

Leather 4-aminoazobenzene test

GB/T 19942-2005

Determination of banned azo dyes in leather and fur chemical tests

GB 19601-2013

Limits and determination of 23 harmful aromatic amines in dye products

GB/T 24101-2009

Limit and determination of 4-aminoazobenzene in dye products

 

Test requirements


Sample type

Textiles, leather, dyes, etc.

Sample size

not less than 20g

Textile products

1. If the textiles are semi-finished products, such as yarns, fabrics, etc., samples need to be cut from the above products.

2. If the product is composed of several textiles, such as clothing; it is necessary to cut samples from all parts that directly and Pocket fabric, product label, drawstring, zipper, imitation fur, sewing thread.

3. If the quality of some parts (logo, sewing thread, small size embroidery) is less than 1g, collect the same parts until it reaches 1g.

4. If the mass of these materials is less than 0.5g, the results are uncertain, and more samples can be requested for confirmation.

5. If the quality of these parts is less than 0.2g, they will not be tested.

6. Cut out the embroidery part together with the base fabric.

dyed textiles

1. All colors of the sample should be tested. (White samples do not need to be tested)

2. If multiple color samples are easier to separate colors and cut, they can be mixed and tested, and a maximum of three colors are allowed to be mixed.

2.1  Multiple colors should be selected from the same part first;

2.2  If 2.1 cannot be met, try to select from the same fabric;

2.3  If the above 2.1 and 2.2 conditions cannot be met, it should be selected from the same technology;

2.4  Cut out the similar mass of each color and weigh 1g; 2.5. If the test result of any aromatic amine in the mixed sample is between 5mg/kg and 30mg/kg It must be tested separately by color.

3. If a variety of color samples are inseparable by physical methods or difficult to separate and cut, mixed testing shall be adopted. Sampling should be based on color composition and ratio.

 

 Test cycle< /strong>


General test cycle        

5WD

Expedited testing cycle

3WD (Leather 4 WD)


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